Shun Kurosaki/Relationship

Ruri Kurosaki
The two are siblings, and seeing from Shun's determination to find her, they had a close relationship. He goes as far as to randomly target any Duelist from LDS in attempt to bargain Reiji Akaba for her. His feelings for his sister is so strong that he didn't hesitate to threaten his own best friend, Yūto, if he feels he's getting in his way. The thought of her capture easily makes him enraged and he will start Duelling mercilessly against anyone affiliated with Academia.

Yūto
Shun and Yūto are best friends, both have known each other for a long time. Although there have been disagreements and differences between their ideas, they have a lot of faith and trust in each other. Yūto acted as a voice of reason for Shun, stopping him whenever he did something reckless out of concern for his well-being. Shun also considered Yūto as his one and only best friend, showing concern when Yūto fought with Yūgo when a Synchro Summon was detected and wished to assist his friend if not stopped by Reiji. Shun becomes worried when he couldn't contact Yūto and angrily accused Yūya of harming and stealing Yūto's card. In his rematch against Dennis, Shun Duelled fiercely on his behalf. Though, despite their strong friendship, Shun doesn't hesitate to threaten Yūto if he feels Yūto getting in his way on saving his sister.

Reiji Akaba
Despite previously being opposing forces, they team up for their own gains. Shun had hoped to bargain Reiji for Ruri, but ended up joining LDS to find more opportunities to find Ruri. In turn, Reiji has informed Shun on what his father is up to. The two share a common goal, to find Reo Akaba and know what he is up to. Shun is shown to not fully trust Reiji and is frequently annoyed when his demands to take action are refused, forcing him to stay back and watch. Reiji often has to request his subordinates keep Shun under vigilance to ensure he doesn't do anything reckless that can affect his plans to recruit Lancers. In spite of his annoyance, Shun usually relents and follows Reiji's instructions.

Lancers
Shun claimed to Crow during their Duel that he doesn't see any other member of the Lancers as comrades. When they were separated during their arrival in the Synchro Dimension, he assumed that they had become lost between dimensions and did not bother to search for them. While he did aid them during their escape from the Facility, he later decided that he couldn't trust them after Dennis was revealed to be from Academia.

Crow Hogan
Shun initially saw Crow as nothing more than another enemy, but their experience with the orphans that Crow looked after and Crow's struggles as a Commons caused him to realize that they had a great deal in common. His demeanor towards Crow changed from that point on, and he genuinely enjoyed the rest of the Duel and smiled when he was defeated. Before parting ways, Shun accepted Crow as a comrade.

Sora Shiun'in
Sora is shown to be very hostile to Shun. When they Dueled for the first time Shun vowed to not to show mercy on the fusion user (not knowing at the time he is a fusion user ) Sora initially treated Shun kindly in their dueled and when he saw Sora entertaining him the he began to talk about the days in Heartland. Realizing that Shun is from Heartland, Sora decide to show his true colors and taunted him really badly, enraging Shun who in return defeated and gravely injured Sora. Sora refused to accept his loss against Shun and develop a deep grudge and hatred for him and when he return to standard Sora successfully got his revenge and defeat Shun brutally.